Diopside, enstatite and forsterite solubilities in H2O and H2O-NaCl solutions at lower crustal and upper mantle conditions

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Solubility of enstatite forsterite in H2O at deep crust/upper mantle conditions: 4 to 15 kbar and 700 to 900°C

Ten reversed brackets of aqueous silica concentration in equilibrium with enstatite (Mg2Si2O6) and forsterite (Mg2SiO4) were determined at 700 to 900°C and 4.35 to 14 kbar. Silica solubilities were measured by a weight loss-weight gain method and by approaching equilibrium from higher and lower silica concentrations. Both single-crystal and fine-grained synthetic enstatite and forsterite starti...

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Quartz solubility in H2O-NaCl and H2O-CO2 solutions at deep crust-upper mantle pressures and temperatures: 2–15 kbar and 500–900°C

The solubility of quartz in H2O-NaCl solutions was measured at 2, 4.35, 10 and 15 kbar and 500–900°C, and at NaCl concentrations up to halite saturation, usually greater than 75 wt.%. Quartz solubility was also measured in CO2-H2O solutions at 10 kbar and 800°C. Solubilities were determined by weight loss of ground and polished quartz crystal fragments which were equilibrated with solutions in ...

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THE SYSTEM DIOPSIDE – FORSTERITE – ENSTATITE AT 5.1 GPa: A TERNARY MODEL FOR MELTING OF THE MANTLE¶

Data determined using a multianvil press are given for liquidus phase relations in the system diopside – forsterite – enstatite (CaMgSi2O6 – Mg2SiO4 – MgSiO3) and extend for a limited distance into the larger ternary system diopside – forsterite – quartz at 5.1 GPa. In the system diopside–enstatite, which cuts across the system diopside – forsterite – quartz and divides it into two smaller tern...

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The solubility of fluorite in H2O and H2O–NaCl at high pressure and temperature

The solubility of fluorite in H2O and H2O–NaCl has been measured at 600–1000 °C, 0.5–2.0 GPa in a piston–cylinder apparatus. Fluorite dissolves congruently at all conditions investigated. The data indicate that the concentration of fluorite dissolved in H2O is low at 600 °C and 0.5 GPa (0.0014 mol/kg H2O) but increases strongly with temperature (T) and pressure (P) to 0.247 mol/kg H2O at 1000 °...

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Solubility of grossular, Ca3Al2Si3O12, in H2O–NaCl solutions at 800 C and 10 kbar, and the stability of garnet in the system CaSiO3–Al2O3–H2O–NaCl

The solubility and stability of synthetic grossular were determined at 800 C and 10 kbar in NaCl–H2O solutions over a large range of salinity. The measurements were made by evaluating the weight losses of grossular, corundum, and wollastonite crystals equilibrated with fluid for up to one week in Pt capsules and a piston-cylinder apparatus. Grossular dissolves congruently over the entire salini...

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ژورنال

عنوان ژورنال: Geochimica et Cosmochimica Acta

سال: 2020

ISSN: 0016-7037

DOI: 10.1016/j.gca.2020.03.035